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Nouvelle publication de l’équipe CIEl : « Characterization of a butterfly flapping dinuclear copper(II) complex and its fleeting mixed-valent Cu(II)Cu(III) counterpart. »

A. Kochem, F. Gennarini, M. Yemloul, M. Orio, N. Le Poul, E. Rivière, M. Giorgi, B. Faure, Y. Le Mest, M. Réglier, A. J. Simaan.

ChemPlusChem 2017, 82, 615-624.

DOI: 10.1002/cplu.201600636

Abstract: A flexible dinuclear copper(II) complex based on a tetraamide ligand that resembles a butterfly flapping its wings is characterized, along with its one-electron oxidized species, which consists of an unstable mixed-valent copper(II)/copper(III) species.[:]